කැල්සියම් කාබයිඩ්

විකිපීඩියා, නිදහස් විශ්වකෝෂය වෙතින්
වෙත පනින්න: සංචලනය, සොයන්න
කැල්සියම් කාබයිඩ්
කැල්සියම් කාබයිඩ්
BaO2structure.jpg
Identifiers
CAS number 75-20-7 YesY
PubChem 6352
Properties
Molecular formula CaC2
Molar mass 64.099 g/mol
Appearance White powder to grey/black crystals
Density 2.22 g/cm3
Melting point

2160 °C, 2433 K, 3920 °F

Boiling point

2300 °C, 2573 K, 4172 °F

Solubility in water decomposes
Structure
Crystal structure Tetragonal [1]
Space group D174h, I4/mmm, tI6
Coordination
geometry
6
Hazards
NFPA 704
NFPA 704.svg
3
3
2
W
 YesY (what is this?)  (verify)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references
Calcium carbide.

Calcium carbide is a chemical compound with the chemical formula of CaC2. The pure material is colorless, but most samples have a color ranging from black to grayish-white, depending on the grade. Its main use industrially is in the production of acetylene and calcium cyanamide.[2]

Production[සංස්කරණය]

Calcium carbide is produced industrially in an electric arc furnace from a mixture of lime and coke at approximately 2000 °C. This method has not changed since its invention in 1888:

CaO + 3 C → CaC2 + CO

The high temperature required for this reaction is not practically achievable by traditional combustion, so the reaction is performed in an electric arc furnace with graphite electrodes. The carbide product produced generally contains around 80% calcium carbide by weight. The carbide is crushed to produce small lumps that can range a few mm up to 50 mm. The impurities are concentrated in the finer fractions. The CaC2 content of the product is assayed by measuring the amount of acetylene produced on hydrolysis. As an example, the British and German standards for the content of the coarser fractions are 295 L/kg and 300 L/kg respectively. Impurities present in the carbide include phosphide, which produces phosphine when hydrolysed.[3]

This reaction was an important part of the industrial revolution in chemistry, and was made possible in the USA as a product of massive amounts of cheap hydro-electric power liberated from Niagara Falls before the turn of the 20th century.

The method for the production in an electric arc furnace was discovered independently by T. L Willson and H. Moissan in 1888 and 1892.[4][5]

Crystal structure[සංස්කරණය]

Pure calcium carbide is a colourless solid. The common crystalline form at room temperature is a distorted rock salt structure with the C22− units lying parallel.[6]

යෙදවුම්[සංස්කරණය]

ඇසිටිලින් නිපැයුම[සංස්කරණය]

The reaction of calcium carbide with water was discovered by Friedrich Wöhler in 1862.

CaC2 + 2 H2O → C2H2 + Ca(OH)2

This reaction is the basis of the industrial manufacture of acetylene, and is the major industrial use of calcium carbide. In China, acetylene derived from calcium carbide remains a raw material for the chemical industry, in particular for the production of polyvinyl chloride. Locally produced acetylene is more economical than using imported oil.[7] Production of calcium carbide in China has been increasing. In 2005 output was 8.94 million tons, with the capacity to produce 17 million tons.[8] In the USA, Europe and Japan consumption is generally declining.[9] Production levels in the USA in 1990s were 236,000 tons per year.[6]

කැල්සියම් cyanamide නිපැයුම[සංස්කරණය]

කැල්සියම් කාබයිඩ් reacts with nitrogen at high temperature to form කැල්සියම් cyanamide:

CaC2 + N2 → CaCN2 + C

Calcium cyanamide is used as fertilizer. It is hydrolysed to cyanamide, H2NCN.[6]

Steel නිපැයුම[සංස්කරණය]

කැල්සියම් කාබයිඩ් is used:

  • in the desulfurisation of iron (pig iron, cast iron and steel)[3]
  • as a fuel in steelmaking to extend the scrap ratio to liquid iron, depending on economics.
  • as a powerful deoxidizer at ladle treatment facilities.

කාබයිඩ් ලාම්පු[සංස්කරණය]

Lit carbide lamp

Calcium carbide is used in carbide lamps, in which water drips on the carbide and the acetylene formed is ignited. These lamps were usable but dangerous in coal mines, where the presence of the flammable gas methane made them a serious hazard. The presence of flammable gases in coal mines led to the miner safety lamp. However, carbide lamps were used extensively in slate, copper and tin mines, but most have now been replaced by electric lamps. Carbide lamps are still used for mining in some less wealthy countries, such as in the silver mines near Potosi, Bolivia. Carbide lamps are also still used by some cavers exploring caves and other underground areas,[10] though they are increasingly being replaced in this use by LED lights. They were also used extensively as headlights in early automobiles, motorcycles and bicycles, although in this application they are also obsolete, having been replaced entirely by electric lamps.[11]

Other uses[සංස්කරණය]

In the ripening of fruit, calcium carbide is used as source of acetylene gas, which is a ripening agent (similar to ethylene).[12]

It is still used in the Netherlands for a traditional custom called Carbidschieten (Shooting Carbide). To create an explosion, carbide and water are put in a milk churn with a lid. Ignition is usually done with a torch. Some villages in the Netherlands fire multiple milk churns in a row as a New Year's Eve tradition.[13] The tradition comes from an old pagan religious practice intended to chase off spirits.

It is used in toy cannons (see Big-Bang Cannon), as well as in bamboo cannons.

Together with calcium phosphide, calcium carbide is used in floating, self-igniting naval signal flares (see Holmes' Marine Life Protection Association).

Calcium carbide is also used in small carbide lamps called carbide candles, which are used for blackening rifle sights to reduce glare. These "candles" are used due to the sooty flame produced by acetylene.

බාහිර සබැඳුම්[සංස්කරණය]

References[සංස්කරණය]

  1. Massalimov, I. A.; Kireeva, M. S.; Sangalov, Yu. A. (2002). Inorganic Materials 38: 363. doi:10.1023/A:1015105922260. 
  2. Patnaik, Pradyot (2003). Handbook of Inorganic Chemical Compounds. McGraw-Hill. ISBN 0070494398. http://books.google.com/?id=Xqj-TTzkvTEC&pg=PA243. Retrieved 2009-06-06. 
  3. 3.0 3.1 Calcium Carbide, Bernhard Langhammer, Ullmann's Encyclopedia of Industrial Chemistry, Wiley Interscience. (Subscription required)
  4. J. T. Morehead, G. de Chalmot (1896). "The Manufacture of Calcium Carbide". Journal of the American Chemical Society 18 (4): 311–331. doi:10.1021/ja02090a001. 
  5. H. Moissan (1892). "Chimie Minérale.- Description d'un nouveau four électrique". Comptes rendus hebdomadaires des séances de l'Académie des sciences 115: 1031. http://gallica.bnf.fr/ark:/12148/bpt6k3071t/f1031.chemindefer. 
  6. 6.0 6.1 6.2 සැකිල්ල:Greenwood&Earnshaw
  7. Ya Dun (2006-01-23). "Troubles in the PVC industry". Hong Kong Trade Development Council. 
  8. "Government takes measures to curb development of calcium carbide sector". BusyTrade.com. 2007-05-16. http://www.busytrade.com/news/newsinfo.php?id=2425. 
  9. Jamie Lacson, Stefan Schlag and Goro Toki (December 2004). "Calcium Carbide". SRI Consulting. 
  10. "Caving equipment and culture (from [[Te Ara Encyclopedia of New Zealand]])".  Wikilink embedded in URL title (help)
  11. Clemmer, Gregg (1987). American Miners' Carbide Lamps: A Collectors Guide to American Carbide Mine Lighting. Westernlore Publications. 
  12. F. B. Abeles and H. E. Gahagan, III (1968). "Abscission: The Role of Ethylene, Ethylene Analogues, Carbon Dioxide, and Oxygen". Plant Physiol. 43 (8): 1255–1258. doi:10.1104/pp.43.8.1255. PMID 16656908. PMC 1087003. http://www.plantphysiol.org/cgi/content/abstract/43/8/1255. 
  13. "an explanation of Carbid Schieten". සම්ප්‍රවේශය 2009-06-06. 

සැකිල්ල:Calcium compounds

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